Kocovsky, Pavel
Articles
Cerny, Miloslav;
Malkov, Andrei V.;
Vrankova, Kvetoslava;
Kocovsky, Pavel, On the selective N-methylation of BOC-protected amino acids. Journal of Organic Chemistry 2009, 74(21), 8425 - 8427, 10.1021/jo9016293 
.
.
Ruzicka, Ales;
Drabina, Pavel;
Malkov, Andrei V.;
Kocovsky, Pavel;
Sedlak, Milos, Synthesis of (R)- and (S)-2-N-methylamino-2,3-dimethylbutanamides and (R)- and (S)-(5-isopropyl-1,5-dimethyl-4,5-dihydro-1H-imidazol-4-on-2-yl)pyridine s. Tetrahedron Asymmetry 2008, 19(3), 384 - 390, 10.1016/j.tetasy.2008.01.016 .
.
Kocovsky, Pavel;
Dvorak, Dalimil, TRANSITION-METAL CATALYSIS IN MICHAEL ADDITION OF β-DICARBONYLS : TUNING OF THE REACTION CONDITIONS. Tetrahedron Letters 1986, 27(41), 5015 - 5018, 10.1016/S0040-4039(00)85121-7 .
.
Kocovsky, Pavel;
Dvorak, Dalimil, TRANSITION-METAL CATALYSIS IN MICHAEL ADDITION OF β-DICARBONYLS: TUNING OF THE REACTION CONDITIONS. Collect. Czech. Chem. Commun. 1988, 53(11A), 2667 - 2674.
Kocovsky, Pavel;
Dvorakova, Hana;
Dvorak, Dalimil;
Srogl, Jiri, Allylic Substitution Catalyzed by a New Molybdenum Complex. Tetrahedron Letters 1995, 36(35), 6351 - 6354, 10.1016/0040-4039(95)01229-B .
.
Kocovsky, Pavel;
Dvorak, Dalimil;
Stary, Ivo, Stereochemistry of molybdenum(0)-catalyzed allylic substitution: The first observation of a syn-syn mechanism. Journal of the American Chemical Society 1995, 117(22), 6130 - 6131.
Malkov, Andrei V.;
Kocovsky, Pavel;
Dvorak, Dalimil;
Baxendale, Ian R.;
Mansfield, Darren J., Molybdenum(II)- and tungsten(II)-catalyzed allylic substitution. Journal of Organic Chemistry 1999, 64(8), 2737 - 2750.
Malkov, Andrei V.;
Kocovsky, Pavel;
Hocek, Michal;
Stambasky, Jan;
Stefko, Martin;
Kapras, Votech;
Kysilka, Ondrej, A modular approach to aryl-C-ribonucleosides via the allylic substitution and ring-closing metathesis sequence. A stereocontrolled synthesis of all four α-/β- and D-/L-C-nucleoside stereoisomers. Journal of Organic Chemistry 2011, 76(19), 7781 - 7803, 10.1021/jo201110z .
.
Kocovsky, Pavel;
Hocek, Michal;
Stambasky, Jan, C-Nucleosides: Synthetic Strategies and Biological Applications. Chemical Reviews 2009, 109(12), 6729 - 6764, 10.1021/cr9002165 .
.
Malkov, Andrei V.;
Kocovsky, Pavel;
Hodacova, Jana;
Kotora, Martin;
Kadlcikova, Aneta;
Westwater, Mary-Margaret;
Gutnov, Andrey;
Ramirez-Lopez, Pedro;
Friscourt, Frederic;
Rankovic, Zoran, New pyridine N-oxides as chiral organocatalysts in the asymmetric allylation of aromatic aldehydes. Tetrahedron 2008, 64(49), 11335 - 11348, 10.1016/j.tet.2008.08.084 .
.
Cisarova, Ivana;
Hrdina, Radim;
Kocovsky, Pavel;
Belokon, Yuri N.;
Bespalova, Natalia B.;
Churkina, Tatiana D.;
Ezernitskaya, Marina G.;
Harutyunyan, Syuzanna R.;
Kagan, Henri B.;
Kochetkov, Konstantin A.;
Larionov, Oleg V.;
Lyssenko, Konstantin A.;
North, Michael;
Polasek, Miroslav;
Peregudov, Alexander S.;
Prisyazhnyuk, Vladimir V.;
Vyskocil, Stepan, Synthesis of α-Amino Acids via Asymmetric Phase Transfer-Catalyzed Alkylation of Achiral Nickel(II) Complexes of Glycine-Derived Schiff Bases. Journal of the American Chemical Society 2003, 125(42), 12860 - 12871, 10.1021/ja035465e .
.
Dufkova, Lenka;
Malkov, Andrei V.;
Kocovsky, Pavel;
Kotora, Martin;
Rulisek, Lubomir;
Ramirez-Lopez, Pedro;
Biedermannova, Lada;
Zhu, Fujiang, On the mechanism of asymmetric allylation of aldehydes with allyltrichlorosilanes catalyzed by QUINOX, a chiral isoquinoline N-oxide. Journal of the American Chemical Society 2008, 130(15), 5341 - 5348, 10.1021/ja711338q .
.
Malkov, Andrei V.;
Kocovsky, Pavel;
Kotora, Martin;
Kysilka, Ondrej;
Kadlcikova, Aneta;
Edgar, Mark, A novel bifunctional allyldisilane as a triple allylation reagent in the stereoselective synthesis of trisubstituted tetrahydrofurans. Chemistry - A European Journal 2011, 17(26), 7162 - 7166, 10.1002/chem.201100513 .
.
Kocovsky, Pavel;
Pour, Milan;
Gogoll, Adolf;
Hanus, Vladimir;
Smrcina, Martin, Corner attack on cyclopropane by thallium (III) ions. A highly stereospecific cleavage and skeletal rearrangement of 3α,5-cyclo-5α-cholestan-6α-ol. Journal of the American Chemical Society 1990, 112(18), 6735 - 6737.
Kocovsky, Pavel;
Hanus, Vladimir;
Smrcina, Martin;
Lorenc, Miroslav;
Sedmera, Petr, Synthesis of Enantiomerically Pure 2,2'-Dihydroxy-1,1'-binaphthyl, 2,2'-Diamino-1,1'-binaphthyl, and 2-Amino-2'-hydroxy-1,1'-binaphthyl. Comparison of Processes Operating as Diastereoselective Crystallization and as Second-Order Asymmetric Transformation. Journal of Organic Chemistry 1992, 57(6), 1917 - 1920, 10.1021/jo00032a055 .
.
Polakova, Jana;
Kocovsky, Pavel;
Vyskocil, Stepan;
Smrcina, Martin, Synthesis of Enantiomerically Pure Binaphthyl Derivatives. Mechanism of the Enantioselective, Oxidative Coupling of Naphthols and Designing a Catalytic Cycle. Journal of Organic Chemistry 1993, 58(17), 4534 - 4538, 10.1021/jo00069a010 .
.
Kocovsky, Pavel;
Langer, Vratislav;
Polasek, Miroslav;
Vyskocil, Stepan;
Smrcina, Martin;
Claxton, Thomas A.;
Hanues, Vladimir;
Chew, Benjamin G. M.;
Zax, David B.;
Verrier, Hugh;
Harper, Kevin, The S2 reaction in the solid state. An unusual, B2 aminolysis of an ester group in crystalline (±)-2-amino-2′-hydroxy-3′-(methoxycarbonyl)-1,1′- binaphthyl elucidated by X-ray diffraction and isotopic labeling. New experimental evidence for linearity in S2 substitution. Journal of the American Chemical Society 1996, 118(2), 487 - 488.
Polakova, Jana;
Kocovsky, Pavel;
Vyskocil, Stepan;
Smrcina, Martin;
Polivkova, Jana, Synthesis and resolution of racemic 2-amino-2′-hydroxy-1,1′-binaphthyl. Collect. Czech. Chem. Commun. 1996, 61(10), 1520 - 1524, 10.1135/cccc19961520 .
.
Polakova, Jana;
Kocovsky, Pavel;
Polasek, Miroslav;
Vyskocil, Stepan;
Hanus, Vladimir;
Smrcina, Martin;
Verrier, Hugh;
Polivkova, Jana;
Sejbal, Jan, Axially chiral 1,1''-binaphthyls with non-identical groups in 2,2'-positions. Synthesis of the enantiomerically pure 2-hydroxy-2'-thiol and substituted 2-amino-2'-thiols. Tetrahedron Asymmetry 1997, 8(4), 537 - 546, 10.1016/S0957-4166(96)00539-3 .
.
Kocovsky, Pavel;
Vyskocil, Stepan;
Smrcina, Martin, A facile synthesis of the enantiopure, nitrogen-substituted 2,2′-diamino-1,1′-binaphthyls as potential ligands for catalytic asymmetric reactions. Collect. Czech. Chem. Commun. 1998, 63(4), 515 - 519.
Kocovsky, Pavel;
Vyskocil, Stepan;
Smrcina, Martin, Synthesis of 2-amino-2'-diphenylphosphino-1,1'-binaphthyl (MAP) and its accelerating effect on the Pd(0)-catalyzed N-arylation. Tetrahedron Letters 1998, 39(50), 9289 - 9292.
Sticha, Martin;
Kocovsky, Pavel;
Hanus, Vladimir;
Smrcina, Martin;
Vyskocil, Stepn;
Jaracz, Stanislav;
Miroslav Poldsek, Synthesis of N-Alkylated and N-Arylated Derivatives of 2-Amino-2′-hydroxy-l, 1′-binaphthyl (NOBIN) and 2,2′-Diamino-1, 1′'-binaphthyl and Their Application in the Enantioselective Addition of Diethylzinc to Aromatic Aldehydes a. Journal of Organic Chemistry 1998, 63(22), 7727 - 7737.
Kocovsky, Pavel;
Polasek, Miroslav;
Vyskocil, Stepan;
Hanus, Vladimir;
Smrcina, Martin, Derivatives of 2-amino-2′-diphenylphosphino-1,1′-binaphthyl (MAP) and their application in asymmetric palladium(O) -catalyzed allylic substitution. Journal of Organic Chemistry 1998, 63(22), 7738 - 7748.
Kocovsky, Pavel;
Vyskocil, Stepan;
Smrcina, Martin, Non-symmetrically substituted 1,1′-binaphthyls in enantioselective catalysis. Chemical Reviews 2003, 103(8), 3213 - 3245, 10.1021/cr9900230 .
.
Kocovsky, Pavel;
Stary, Ivo, Steric Control of Epoxidation by Carbamate and Amide Groups. Evidence for the Carbonyl-Directed Epoxidation. Journal of Organic Chemistry 1990, 55(10), 3236 - 3243, 10.1021/jo00297a047 .
.
Turecek, Frantisek;
Kocovsky, Pavel;
Stary, Ivo, ON THE DECEPTIVE BEHAVIOR OF tri-n-BUTYLTIN HYDRIDE IN THE REDUCTION OF ACETATES OF SOME BROMOHYDRINS. A STEREOSPECIFIC RADICAL REARRANGEMENT. Tetrahedron Letters 1986, 27(13), 1513 - 1516, 10.1016/S0040-4039(00)84300-2 .
.
Kocovsky, Pavel;
Stary, Ivo, SYNTHESIS OF SOME ALLYLIC ACETOXY DERIVATIVES IN THE STEROID SERIES. Collect. Czech. Chem. Commun. 1985, 50(5), 1227 - 1238.
Turecek, Frantisek;
Kocovsky, Pavel;
Stary, Ivo;
Hanus, Vladimir, ELECTROPHILIC ADDITIONS TO 10β-VINYL CHOLESTANE DERIVATIVES. Collect. Czech. Chem. Commun. 1983, 48(10), 2994 - 3019.
Turecek, Frantisek;
Kocovsky, Pavel;
Stary, Ivo;
Zajicek, Jaroslav;
Vasickova, Sona, STEREO- AND REGIO-CONTROL OF ELECTROPHILIC ADDITIONS TO CYCLOHEXENE SYSTEMS BY NEIGHBOURING GROUPS: PARTICIPATION OF ALLYLIC AND HOMOALLYLIC ESTER GROUPS IN HYPOBROMOUS ACID ADDITION TO SOME 5-UNSATURATED CHOLESTANE DERIVATIVES. Journal of the Chemical Society - Perkin Transactions 1 1988, 2297 - 2304.
Kocovsky, Pavel;
Stary, Ivo;
Zajicek, Jaroslav, Stereochemistry of the palladium-catalyzed allylic substitution: The synanti dichotomy in the formation of (π-allyl)palladium complexes and their equilibration. Tetrahedron 1992, 48(35), 7229 - 7250, 10.1016/S0040-4020(01)88263-6 .
.
Kocovsky, Pavel;
Stary, Ivo, The First Observation of Syn-Anti Dichotomy in the Formation of (π-Allyl)palladium Complexes. Journal of the American Chemical Society 1989, 111(13), 4981 - 4982, 10.1021/ja00195a063 .
.
Kocovsky, Pavel;
Stary, Ivo;
Stara, Irena G., Palladium(0)-Catalyzed Allylic Substitution with Allylic Alkoxides as Substrates. Tetrahedron 1994, 50(2), 529 - 538.
Kocovsky, Pavel;
Stary, Ivo;
Stara, Irena G.;
Abbott, Andrew P.;
Cheung, Cherie S. M.;
Lonergan, Gillian R., Electrochemistry of quaternary ammonium binaphthyl salts. Chemical Communications 1999(7), 641 - 642.
Malkov, Andrei V.;
Kocovsky, Pavel;
Stary, Ivo;
Langer, Vratislav;
Gouriou, Laure;
Lloyd-Jones, Guy C.;
Spoor, Paul;
Vinader, Victoria, Asymmetric allylic substitution catalyzed by C-symmetrical complexes of molybdenum: Structural requirements of the ligand and the stereochemical course of the reaction. Chemistry - A European Journal 2006, 12(26), 6910 - 6929, 10.1002/chem.200501574 .
.