Detail of compound @ czechem

Molecular Formula: C₄H₃F₃O₃

Molecular weight: 156.0600296

InChi: InChI=1S/C4H3F3O3/c1-10-3(9)2(8)4(5,6)7/h1H3

InChi Key: XGLLQDIWQRQROJ-UHFFFAOYSA-N

SMILES: C(=O)(C(F)(F)F)C(=O)OC

Chemical Name
CF3C(O)CO2Me
CF3COCOOMe
MeTFP
methyl 4,4,4-trifluoro-2,3-dioxobutanoate
methyl trifluoromethylpyruvate
methyl trifluoropyruvate
MTFP

External Links
PubChem

Ondracek, Jan
Cejka, Jan
Paleta, Oldrich
Kvicala, Jaroslav
Dolensky, Bohumil
Palecek, Jiri

Articles

Ondracek, Jan; Cejka, Jan; Paleta, Oldrich; Kvicala, Jaroslav; Dolensky, Bohumil, Preparation of new trifluoromethyl substituted Tri- and tetracyclic heterocycles with peganin skeleton from a methyl 3,3,3-trifluoropyruvate/2-aminobenzylamine adduct. Tetrahedron Letters 1996, 37(38), 6939 - 6942, 10.1016/0040-4039(96)01517-1

Paleta, Oldrich; Kvicala, Jaroslav; Palecek, Jiri, Fluorinated butanolides and butenolides - Part 9. Synthesis of 2-(trifluoromethyl)butan-4-olides by Wittig reaction using methyl 3,3,3-trifluoropyruvate. Journal of Fluorine Chemistry 2002, 113(2), 177 - 183, 10.1016/S0022-1139(01)00543-7

Paleta, Oldrich; Kvicala, Jaroslav; Dolensky, Bohumil; Palecek, Jiri, Methyl 3,3,3-trifluoropyruvate: An improved procedure starting from hexafluoropropene-1,2-oxide; identification of byproducts. Journal of Fluorine Chemistry 2002, 115(1), 67 - 74, 10.1016/S0022-1139(02)00007-6

Paleta, Oldrich; Kvicala, Jaroslav; Dolensky, Bohumil, Methyl 3,3,3-trifluoropyruvate hemiaminals: Stability and transaminations. Journal of Fluorine Chemistry 2005, 126(5), 745 - 751, 10.1016/j.jfluchem.2005.02.020

Paleta, Oldrich; Kvicala, Jaroslav; Dolensky, Bohumil; Palecek, Jiri, Three-component (Domino) reaction affording substituted pyrroloquinazolines: Cyclization regioselectivity and stereoselectivity. European Journal of Organic Chemistry 2013(7), 1262 - 1270, 10.1002/ejoc.201201356

Paleta, Oldrich; Kvicala, Jaroslav; Dolensky, Bohumil; Palecek, Jiri, New nucleophilic rearrangement in the mechanism of the three-component domino cyclisation affording fluoroalkylated (pyrrolo)quinazolines. Journal of Fluorine Chemistry 2014, 157, 1 - 11, 10.1016/j.jfluchem.2013.10.017